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Radioactive tracer technology (RATT™) is an important tool for measuring real-time wear in operating engines and other mechanical systems. The use of this technology provides important wear information that is not available by other, more conventional wear measurement methods. The technology has advanced to the point where several components can be interrogated simultaneously, and new methods have extended the method to materials that are normally not amenable to radioactive tracer evaluation. In addition, sensitivity has increased so that the onset of wear can be detected long before practical with non-tracer methods. This improves the ability to measure and determine cause and effect relationships, thus providing a better understanding of wear responses to specific operating conditions and to changes in operating conditions. This paper reviews the radioactive tracer process and recent improvements that have extended its reach in both automotive and non-automotive applications.

Two large, heavy light-duty gasoline vehicles (2004 model year Ford F-150 with a 5.4 liter V8 and GMC Yukon Denali with a 6.0 liter V8) were baselined for emission performance over the FTP driving cycle in their stock configurations. Advanced emission systems were designed for both vehicles employing advanced three-way catalysts, high cell density ceramic substrates, and advanced exhaust system components. These advanced emission systems were integrated on the test vehicles and characterized for low mileage emission performance on the FTP cycle using the vehicle's stock engine calibration and, in the case of the Denali, after modifying the vehicle's stock engine calibration for improved cold-start and hot-start emission performance.

An electromagnetic valve actuation (EVA) system was developed and applied to a Kohler Command Series engine. Engine development and testing was conducted for the purpose of evaluating the performance of the EVA-equipped engine, running on natural gas, in an engine-test laboratory environment. As part of this effort, a personal computer-based engine control system, which managed the fueling, ignition, throttling, and intake/exhaust valve control functions, was developed. The evaluation included an investigation into increasing engine power output and full load efficiency, as well as increased part load efficiency. Techniques including optimized valve events as a function of operating condition, and throttleless operation using early and late intake valve closing are presented. Engine simulation results are compared with actual engine data and presented in this paper.

Horiba on-board diesel exhaust particulate sampler (OBS-PM) is a filter based partial flow particulate sampling system used for On-board diesel particulate matter (PM) measurement. It takes sample from either raw or diluted exhaust. It can run at constant dilution ratios or at variable dilution ratios with proportional control on the sample flow. The diluted exhaust moves through a pre-weighed 47 mm particulate filter and PM is collected on the filter. By weighing the loaded sample filter, PM emission from the engine or the vehicle can be determined. The performance of the OBS-PM meets most of requirements for a real-time partial flow sample system (PFSS) recommended by ISO 16183 [2]. The physical size and the power consumption of the instrument are minimized. It is powered with four 12 volts batteries, and can be installed on a vehicle for real-world PM emission evaluation.

In 2005, the United States Environmental Protection Agency (EPA) and Southwest Research Institute (SwRI) embarked on a mission to help the city of Beijing, China, clean its air. Working with the Beijing Environmental Protection Bureau (BEPB), the effort was a pilot diesel retrofit demonstration program involving three basic retrofit technologies to reduce particulate matter (PM). The three basic technologies were the diesel oxidation catalyst (DOC), the flowthrough diesel particulate filter (FT-DPF), and the wallflow diesel particulate filter (WF-DPF). The specific retrofit systems selected for the project were verified through the California Air Resources Board (CARB) or the EPA verification protocol [1]. These technologies are generally verified for PM reductions of 20-40 percent for DOCs, 40-50 percent for the FT-DPF, and 85 percent or more for the high efficiency WF-DPF.

A novel urea evaporation and mixing device has been developed to improve the overall performance of a urea-SCR system. The device was tested with a MY2007 Cummins ISB 6.7L diesel engine equipped with an SCR aftertreatment system. Test results show that the device effectively improved the overall NO conversion efficiency of the SCR catalyst over both steady-state and transient engine operating conditions, while NH₃ slip from the catalyst decreased.

Diesel particulate filters (DPF), known as traps in the mid-to late 1970s, were being developed for on-highway diesel applications. However, advanced engine design and in-cylinder engineering enabled diesel engines and vehicles to meet extremely low emission limits, including those of particulate matter (PM) without the need for DPF's or other auxiliary emission control devices. Late in 2000, the US EPA finalized its on-highway heavy-duty diesel emission standards, thus ending speculations regarding its stringency and establishing the lowest limits ever. The new nitric oxides (NOX) and PM limits are seen as technology-forcing. For NOX emissions, the debate rages on among the technical community about the merits of NOX adsorbers and urea selective catalytic reduction. On the other hand, there seems to be little doubt about DPF's as the technical solution for PM.

Increasing fuel costs and the desire for reduced dependence on foreign oil has brought the diesel engine to the forefront of future medium-duty vehicle applications in the United States due to its higher thermal efficiency and superior durability. The main obstacle to the increased use of diesel engines in this platform is the upcoming extremely stringent, Tier 2 emission standard. In order to succeed, diesel vehicles must comply with emissions standards while maintaining their excellent fuel economy. The availability of technologies such as common rail fuel injection systems, low sulfur diesel fuel, NOX adsorber catalysts (NAC), and diesel particle filters (DPFs) allow the development of powertrain systems that have the potential to comply with these future requirements. In meeting the Tier 2 emissions standards, the heavy light-duty trucks (HLDTs) and medium-duty passenger vehicles (MDPVs) will face the greatest technological challenges. In support of this, the U.S.

The 2007 emission standards for both light-duty and heavy-duty diesel vehicles remain a challenge. A level of about 90% NOx conversion is required to meet the standards. Technologies that have the most potential to achieve very high NOx conversion at low temperatures of diesel exhaust are lean NOx traps (LNTs) and Selective Catalytic Reduction (SCR) of NOx using aqueous urea, typically known as Urea SCR. The LNT has the advantage of requiring no new infrastructure, and does not pose any new customer compliance issues. However, Urea SCR has high and durable NOx conversion in a wider temperature window, a lower equivalent fuel penalty, and lower system cost. On a technical basis, Urea SCR has the best chance of meeting the 2007 NOx targets. This paper reviews the results of some demonstration programs for both light-and heavy-duty applications.

Results of engine bench tests on a 1998 heavy-duty diesel engine have confirmed the emissions reduction performance of a U.S. Environmental Protection Agency (EPA) registered platinum/cerium bimetallic fuel borne catalyst (FBC) used with several different catalyzed and uncatalyzed diesel particulate filters (DPF's). Performance was evaluated on both a 450ppm sulfur fuel (No.2 D) and a CARB 50ppm low sulfur diesel (LSD) fuel. Particulate emissions of less than 0.02g/bhp-hr were achieved on several combinations of FBC and uncatalyzed filters on 450ppm sulfur fuel while levels of 0.01g/bhp-hr were achieved for both catalyzed and uncatalyzed filters using the FBC with the low sulfur CARB fuel. Eight-mode steady state testing of one filter and FBC combination with engine timing changes produced a 20% nitrogen oxide (NOx) reduction with particulates (PM) maintained at 0.01g/bhp-hr and no increase in measured fuel consumption.

The Tank-Automotive RD&E Center periodically conducts foreign materiel evaluations to assess the current state of the art for ground vehicle technologies. The Propulsion Laboratory is conducting performance evaluations of an opposed-piston two-stroke diesel tank engine produced by the Kharkov Design Bureau in Ukraine. A key factor in the performance of all two-stroke engines is the scavenging process, which determines how well the cylinders are emptied of exhaust and filled with fresh air. The overall air flow rate is not sufficient to determine this, as a significant amount of air may be lost through the exhaust ports during the scavenging process. The inlet tracer gas method was employed to provide the additional data required. With methane as the tracer, it produced reasonable and consistent data over a wide range of engine speeds and loads. The inlet tracer gas method was found to be an effective tool for measuring the scavenging performance of a running two-stroke diesel engine.

Automotive catalytic converters must provide a very high level of mechanical and thermal durability to maintain performance during their 100,000 to 150,000 mile life expectancy. The work reported herein characterizes the converter as a base (can) excited spring (mat material) supported mass (substrate). A mat material coupon test apparatus was developed for the purpose of providing parameter data for the converter model in the form of stiffness and material loss factor data as a function of shear deflection across the mat. An intumescent mat material was chosen and its dynamic properties evaluated for a range of converter operating parameters. The mat material response properties were placed into a mat material database as a function of gap bulk density, substrate temperature, and temperature gradient across the mat.

The current operation of the International Space Station (ISS) calls for the oxygen used by the occupants to be vented overboard in the form of CO2, after the CO2 is scrubbed from the cabin air. Likewise, H2 produced via electrolysis in the oxygen generator is also vented. NASA is investigating the use of the Sabatier process to combine these two product streams to form water and methane. The water is then used in the oxygen generator, thereby conserving this valuable resource. One of the technical challenges to developing the Sabatier reactor is transferring CO2 from the Carbon Dioxide Removal Assembly (CDRA) to the Sabatier reactor at the required rate, even though the CDRA and the Sabatier reactor operate on different schedules. One possible way to transfer and store CO2 is to use a mechanical compressor and a storage tank.

Vehicle designers make use of vehicle performance programs such as RAPTOR™ to predict the performance of concept vehicles over ranges of industry standard drive cycles. However, the accuracy of such predictions may be greatly influenced by factors requiring more specialist simulation capabilities. For example, fuel economy prediction will be heavily influenced by the performance of the engine cooling system and its impact on the vehicle's aerodynamic drag, and the load from the air-conditioning system. To improve the predictions, specialist simulation capabilities need to be applied to these aspects, and brought together with the vehicle performance calculations through co-simulation. This paper describes the approach used to enable this cosimulation and the benefits achieved by the vehicle designer.

The use of a partial flow sampling system (PFSS) to measure nonroad steady-state diesel engine particulate matter (PM) emissions is a technique for certification approved by a number of regulatory agencies around the world including the US EPA. Recently, there have been proposals to change future nonroad tests to include testing over a nonroad transient cycle. PFSS units that can quantify PM over the transient cycle have also been discussed. The full flow constant volume sampling (CVS) technique has been the standard method for collecting PM under transient engine operation. It is expensive and requires large facilities as compared to a typical PFSS. Despite the need for a cheaper alternative to the CVS, there has been a concern regarding how well the PM measured using a PFSS compared to that measured by the CVS. In this study, three PFSS units, including AVL SPC, Horiba MDLT, and Sierra BG-2 were investigated in parallel with a full flow CVS.

In the United States, most school buses are powered by diesel engines. Some have advocated replacing diesel school buses with natural gas school buses, but little research has been conducted to understand the emissions from school bus engines. This work provides a detailed characterization of exhaust emissions from school buses using a diesel engine meeting 1998 emission standards, a low emitting diesel engine with an advanced engine calibration and a catalyzed particulate filter, and a natural gas engine without catalyst. All three bus configurations were tested over the same cycle, test weight, and road load settings. Twenty-one of the 41 “toxic air contaminants” (TACs) listed by the California Air Resources Board (CARB) as being present in diesel exhaust were not found in the exhaust of any of the three bus configurations, even though special sampling provisions were utilized to detect low levels of TACs.

Particle size distribution, number, and mass emissions from the exhaust of a 92 kW 1999 Isuzu 6BG1 nonroad naturally aspirated diesel engine were measured. The engine exhaust was equipped with a Dry System Technologies® (DST) auxiliary emission control device that included an oxidation catalyst, a heat exchanger, and a disposable paper particulate filter. Particle measurement was taken during the ISO 8178 8-mode test for engine out and engine with the DST using a scanning mobility particle sizer (SMPS) in parallel to the standard filter method (SFM), specified in 40 CFR, Part 89. The DST efficiency of removing particles was about 99.9 percent based on particle number, 99.99 percent based on particle mass derived from number and size. However, the efficiency based on mass derived from the SFM was much lower on the order of 90 to 93 percent.

This paper describes the findings of a laboratory effort to demonstrate improved automotive exhaust emission control with a cold-start hydrocarbon collection system. The emission control strategy developed in this study incorporated a zeolite molecular sieve in the exhaust system to collect cold-start hydrocarbons for subsequent release to an active catalytic converter. A prototype emission control system was designed and tested on a gasoline-fueled vehicle. Continuous raw exhaust emission measurements upstream and downstream of the zeolite molecular sieve revealed collection, storage, and release of cold-start hydrocarbons. Federal Test Procedure (FTP) emission results show a 35 percent reduction in hydrocarbons emitted during the cold-transient segment (Bag 1) due to adsorption by the zeolite.

Recent legislation, including the California Clean Air Act of 1988 and the Federal Clean Air Act Amendment of 1990, includes off-road engines, equipment, and vehicles as targets for new exhaust emissions regulations. The Santa Barbara County Air Pollution Control District in cooperation with EXXON USA is conducting a major Low NOx Demonstration Program including mobile sources, construction equipment, and offshore equipment. As a part of this program, an existing backhoe has been retrofitted with a low NOx engine and demonstrated in the field. This paper discusses the work performed to allow Case model 580 backhoes to be retrofitted with Cummins 4BTAA3.9 on-highway turbocharged diesel engines. A standard production conversion kit can be used to mount the new engines in place of the older existing JI Case engines in some models while other newer models already have 4B3.9 engines. In addition, an air-to-air aftercooler and associated plumbing was designed and installed.

Ideally, complete decomposition of urea should produce only two products in active Selective Catalytic Reduction (SCR) systems: ammonia and carbon dioxide. In reality, urea decomposition reaction is a two-step process that includes the formation of ammonia and isocyanic acid as intermediate products via thermolysis. Being highly reactive, isocyanic acid can initiate the formation of larger molecular weight compounds such as cyanuric acid (CYN), biuret (BIU), melamine (MEL), ammeline (AML), ammelide (AMD), and dicyandimide (DICY). These compounds can be responsible for the formation of deposits on the walls of the decomposition reactor in urea SCR systems. Composition of these deposits varies with temperature exposure, and under certain conditions can create oligomers that are difficult to remove from exhaust pipes. Deposits can affect efficiency of the urea decomposition, and if large enough, can inhibit the exhaust flow and negatively impact ammonia distribution on the SCR catalyst.